Publications

Publications
2020～

Ru(IV)–Ru(IV), Ru(III)–Ru(IV), and Ru(III)–Ru(III) complexes having a sulfato bridging ligand on the doubly oxido-/hydroxio-bridged core, and their crystallographic and electronic structures
T. Misawa-Suzuki*, Y. Kataoka, S. Mafune, T. Niwa, H. Nagao, Dalton Trans., 2025, 54, 2937-2949.

Co(III)-Co(II)-Co(III) Edge-Sharing Trinuclear Complexes Having the Doubly Methoxido-Bridged Core Bridged by Acetato Ligand
R. Ito, T. Misawa-Suzuki*, H. Nagao,Inorg. Chem. Commun., 2024, 169, 113060.

Pyrazine Coordinated Dinuclear and Mononuclear Ruthenium Complexes Formed via the Conversion of the Triply Chlorido-Bridged Diruthenium(II) Complex
K. Nakayama, T. Misawa-Suzuki*, H. Nagao*, Inorg. Chem., 2024, 63, 11209-11218.

Syntheses of Ruthenium Complexes Bearing Asymmetric Tridentate Ethyl(2-pyridylmethyl)aminoacetate
T. Misawa-Suzuki, I. Okuda, K. Takeda, H. Nagao*, Inorg. Chimica Acta, 2024, 55, 122168.

Water oxidation utilizing a ruthenium complex featuring a phenolic moiety inspired by the oxygen-evolving centre (OEC) of photosystem II
Y. Kumagai, R. Takabe, T. Nakazono, M. Shoji*, H. Isobe, K.Yamaguchi, T. Misawa-Suzuki, H. Nagao, T. Wada*, Sustainable EnergyFuels, 2024, 8, 905–913.

Ru(IV)-Ru(IV) Complexes Having the Doubly Oxido-Bridged Core with a Bridging Carbonato or Hydrogencarbonato Ligand
T. Misawa-Suzuki*, H. Nagao*, Dalton Trans., 2023, 52, 2863–2871.

Recognition of D-Glucose in Water with Excellent Sensitivity, Selectivity, and Chiral Selectivity Using γ-Cyclodextrin and Fluorescent Boronic Acid Inclusion Complex Having Pseudo-Diboronic Acid Moiety
Y. Suzuki*, Y. Mizuta, A. Mikagi, T. Misawa-Suzuki, Y. Tsuchido, T. Sugaya, T. Hashimoto, K. Ema, T. Hayashita* ACS Sens., 2023, 8, 218–227.

Characterization of the active species of methane monooxygenase
T. Misawa-Suzuki, Chemistry, Kagakudojin, 2022, vol. 8.

Geometry and Electronic Structures of Cobalt(II) and Iron(III) Complexes Bearing Bis(2-pyridylmethyl)ether or Alkylbis(2-pyridylmethyl)amine
T. Misawa-Suzuki*, R. Ikeda, R. Komatsu, R. Toriba, R. Miyamoto, H. Nagao*, Polyhedron, 2022, 218, 115735-115743.

Structure and Functions of Dinuclear Ruthenium Complexes with the Oxido-Bridged Core
T. Misawa-Suzuki*, Bull. Jpn. Soc. Coord. Chem. 2021, 78, 40-43.

N-C Bond Formation Between Two Anilines Coordinated to a Ruthenium Center in a Cis-form Affording a 3,5-Cyclohexadiene-1,2-diimine Moiety
N. Tomioka, S. Nanbu, T. Misawa-Suzuki, H. Nagao*, RSC Adv., 2021, 11, 36644-36650.

N-N Bond Cleavage upon Reduction and Protonation of Phenylazophenylate Coordinated to Ruthenium Complex
N. Tomioka, T. Misawa-Suzuki, H. Nagao*, Polyhedron, 2021, 202, 115193-115201. ＊Selected as a cover graphic
Life with the Oxido-Bridged Metal Complexes
T. Misawa-Suzuki, CanApple（Consortium of All Nippon Artificial Photosynthesis Project for Living Earth）Newsletter 184, 2021年。
Material Conversion on the Global Nitrogen Cycle
H. Nagao, CanApple（Consortium of All Nippon Artificial Photosynthesis Project for Living Earth）Newsletter 182, 2021年。

Synthesis of Carbonato- and Doubly Oxido-Bridged Diruthenium(III,IV) Complex and Reactions with Cations
T. Misawa-Suzuki*, S. Mafune, H. Nagao*, Inorg. Chem., 2021, 60, 9996-10005.

Preparation and antioxidant study of silver nanoparticles of Microsorum pteropus methanol extract
N. C. Chick, T. Misawa-Suzuki, Y. Suzuki, T. Usuki*, Bioorg. Med. Chem. Lett., 2020, 30, 127526-127529.

Interactions of ruthenium(III) complexes bearing bis(2-pyridylcarbonyl)aminate with cations at the carbonyl group
T. Misawa-Suzuki, M. Etoh, H. Nagao*, Bull. Chem. Soc. Jpn., 2020, 93, 1412-1418.

Framework Conversion of Oxido-Bridged Dinuclear Ruthenium Complexes
T. Misawa-Suzuki*, T. Watanabe, M. Okamura, S. Nanbu, H. Nagao*, Inorg. Chem., 2020, 59, 612-622.

2010 ~ 2019

Halogeno Ligand-Substitution Reactions of Ruthenium Complexes Bearing Ethylbis(2-pyridylmethyl)amine to Synthesize New Complexes
T. Misawa-Suzuki*, N. Tomioka, Y. Osawa, H. Nagao*, Eur. J. Inorg. Chem., 2019, 4040-4047.

Polymer synthesis with the use nitrosylruthenium complexes
H. Nagao, H. Ohno, M. Rikukawa, Patent #6562351, 2019。

Triply Bridged Dinuclear Ruthenium Complexes Bearing Alkylbis(2-pyridylmethyl)amine in the Mixed-Valence State of Ru(II)-Ru(III)
T. Misawa-Suzuki, K. Matsuya, T. Watanabe, H. Nagao*, Dalton Trans., 2018, 47, 16182-16189.

Nitrosylruthenium Complexes as Polymerization Catalysts for Acrylonitrile in DMF
H. Nagao*, T. Misawa-Suzuki, N. Tomioka, H. Ohno, M. Rikukawa, Chemistry - An Asian Journal, 2018, 13, 3014-3017.

Acetylacetonato-based pincer-type nickel(ii) complexes: Synthesis and catalysis in cross-couplings of aryl chlorides with aryl Grignard reagents
E. Asano, Y. Hatayama, N. Kurisu, A. Ohtani, T. Hashimoto, Y. Kurihara, K. Ueda, S. Ishihara, H. Nagao, Y. Yamaguchi*, Dalton Trans., 2018, 47, 8003-8012.

Reactions of Azides Coordinated to Ruthenium(II) Centers with Haloalkanes To Afford Nitrogen-Containing Moieties
Y. Sumoge, S. Nanbu, H. Nagao*, Eur. J. Inorg. Chem., 2017, 2998-3007.

Formation of doubly nitrosyl-bridged diruthenium complex bearing tridentate ethylbis(2-pyridylethyl)amine via conversion of nitrate
T. Suzuki, S. Hemmi, Y. Kazama, D. Oyama, H. Nagao*, Bull. Chem. Soc. Jpn., 2017, 90, 1067-1072.

Dinuclear Ruthenium(III)-Ruthenium(IV) Complexes, Having a Doubly Oxido-Bridged and Acetato- or Nitrato-Capped Framework
T. Suzuki, Y. Suzuki, T. Kawamoto, R. Miyamoto, S. Nanbu, H. Nagao*, Inorg. Chem., 2016, 55, 6830-6832.

Synthesis and Structures of Mixed-Valence Oxido-Bridged Diruthenium Complexes Bearing Ethylbis(2-pyridylmethyl) amine
T. Suzuki, K. Matsuya, T. Kawamoto, H. Nagao*, Eur. J. Inorg. Chem., 2014, 722-727 Special Issue - Water Oxidation Chemistry.

Formation of bis(2-pyridylcarbonyl)aminate by oxidation of ethylbis(2-pyridylmethyl)amine on the trichloridoruthenium(III) complex
H. Nagao*, N. Shimura, H. Yonezawa, Dalton Trans., 2014, 43, 15391-15397.

Development of the Ruthenium Complex - Ionic Liquid Reaction System for CO₂ Conversion
ENEOS Technical Review 56, 8-11, 2014年。

Twisted coordination mode of bis(N-heterocyclic carbene) ligands in octahedral geometry of group 6 transition metal complexes: Synthesis, structure, and reactivity
K. Ogata, Y. Yamaguchi*, Y. Kurihara, K. Ueda, H. Nagao, T. Ito, Inorg.Chimica.Acta, 2012, 390, 199-209.

Characterization of the E Isomer of Tetrasubstituted [5]Cumulene and Trapping of the Z Isomer as a Zirconocene Complex
N. Suzuki*, N. Ohara, K. Nishimura, Y. Sakaguchi, S. Nanbu, S. Fukui, H. Nagao, Y. Masuyama, Organometallics, 2011, 30, 3544–3548.

Synthesis and Characterization of Ethylbis(2-pyridylethyl)amineruthenium Complexes and Two Different Types of C–H Bond Cleavage at an Ethylene Arm
S. Fukui, A. Kajihara, T. Hirano, F. Sato, N. Suzuki, H. Nagao*, Inorg. Chem., 2011, 50, 4713–4724.

Formation and Structure of an (Iminium ion)ruthenium Complex and Reaction of the Iminium Ion Moiety with Alcohols
S. Fukui, N. Suzuki, T. Wada, K. Tanaka, H. Nagao*, Organometallics, 2011, 29, 1534–1536.

2000 ~ 2009

Redox Reactions of Ruthenium Complexes Containing Pyridyl Ligands for Conversion of Nitrogen-Containing Compunds
H. Nagao, Bull. Jpn. Soc. Coord. Chem. 2009, 54 22-37.

A mixed-valence diruthenium complex, triply bridged by mixed-moieties of chloro and methoxo ligands
K. Matsuya, S. Fukui, Y. Hoshino, H. Nagao*, Dalton Trans., 2009, 7876-7878.

Reactions of Ruthenium Complexes Having Pyridyl-Containing Ligands, 2-Pyridinecarboxylato and 2,2′-Bipyridine, with an Azide Ion: Formation of Nitrido-Bridged Diruthenium Complexes
S. Matsumura, K. Shikano, T. Oi, N. Suzuki, H. Nagao*, Inorg. Chem., 2008, 47 9125-9127.

Synthesis and Characterization of Ruthenium Complexes Having Tridentate N-Ethyl-N,N-bis(2-pyridylmethyl)amine Coordinating in a Facial or Meridional Fashion
Y. Shimizu, . Fukui, T. Oi, H. Nagao*, Bull. Chem. Soc. Jpn., 2008, 81, 1285-1295.

cis-trans geometrical isomerization of bis(2-pyridinecarboxylato)nitrosylruthenium complex accompanying electrochemical one-electron reduction
S. Fukui, Y. Shimamura, Y. Sunamoto, T. Abe, T. Hirano, T. Oi, H. Nagao*, Polyhedron, 2007, 16, 4645-4652.

Synthesis of Nitrosylruthenium Complexes Containing 2,2':6',2"-Terpyridine by Reactions of Alkoxo Complexes with Acids
H. Nagao*, K. Enomoto, Y. Wakabayashi, G. Komiya, T. Hirano, T. Oi, Inorg. Chem., 2007, 46, 1431–1439.

Concerted proton-electron transfer in the oxidation of hydrogen-bonded phenols
I. J. Rhile, T. F. Markle, H. Nagao, A. G. DiPasquale, O. P. Lam, M. A. Lockwood, K. Rotter, J. M. Mayer*, J. Am. Chem. Soc. 2007, 46, 6075-6088.

Formation of a Methyleneimine Moiety by Reaction of a Ru^II-Coordinated Azide Ion with Methyl Iodide
H. Nagao*, T. Kikuchi, M. Inukai, A. Ueda, T. Oi, N. Suzuki, M. Yamasaki, Angew. Chem. Int. Ed., 2006, 45, 3131-3133.

Synthesis, electrochemistry and mixed-valence state of dinuclear tris(acetylacetonato)ruthenium(III) complexes bridged by sulfur atoms at the γ-position of acetylacetonate
A. Endo*, M. Sibasaki, H. Nagao, K. Shimizu, Inorg. Chim. Acta, 2004, 357, 3443-3450.

Regulation of geometry around the ruthenium center of bis(2-pyridinecarboxylato) complexes by the nitrosyl moiety: Syntheses, structures, and theoretical studies
T. Hirano, T. Oi, H. Nagao*, K. Morokuma, Inorg. Chem., 2003, 42, 6575–6583.

Reactions of acetonitrile coordinated to a nitrosylruthenium complex with H₂O or CH₃OH under mild conditions: Structural characterization of imido-type complexes
H. Nagao*, T. Hirano, N. Tsuboya, S. Shiota, M. Mukaida, T. Oi, M Yamasaki, Inorg. Chem., 2002, 41, 6267–6273.

Cis-trans isomerization of {RuNO}⁶-type nitrosylruthenium complexes containing 2-pyridinecarboxylate and structural characterization of a m-H₃O₂ bridged dinuclear nitrosylruthenium complex
T. Hirano, M. Kuroda, N. Takeda, M. Hayashi, M. Mukaida, T. Oi, H. Nagao*, J. Chem. Soc., Dalton Trans., 2002, 2158-2162.

Synthesis, characterization and reactivity of a series of dinuclear copper complexes bearing the ligand bis[3-(2-hydroxybenzylideneamino)phenyl] sulfone and derivatives
A.M. Guidote, K. Ando, K. Terada, Y. Kurusu, H. Nagao, Y. Masuyama*, Inorg. Chim. Acta, 2001, 324, 203-211.

Reactions of [RuCl₂(NO)(terpy)]⁺ (terpy=2,2':6',2"-terpyridine) with mono anions such as NO₂^-, Br^- and N₃^-, and structural studies on terpyridineruthenium having a nitrosyl ligand
T. Hirano, K. Ueda, M. Mukaida, H. Nagao*, T. Oi, J. Chem. Soc., Dalton Trans., 2001, 2341-2345.

Synthesis and characterization of polypyridineruthenium(II) complexes containing a linear ambidentate ligand, NCO⁻ or NCS⁻, and reaction of isocyanato complexes under acidic conditions
H. Nagao*, D. Ooyama, T. Hirano, H. Naoi, M. Shimada, S. Sasaki, N. Nagao, M. Mukaida, T. Oi, Inorg. Chim. Acta, 2001, 320, 60-66.

Syntheses and characterization of homodinuclear manganese and cobalt complexes bridged by a hemiacetal or by an acetato group in a m-(h²:h¹) bridging mode
A.M. Guidote, K. Ando, Y. Kurusu, H. Nagao, Y. Masuyama*, Inorg. Chim. Acta, 2001, 314, 27-36.

Behaviors of the One-Electron Reduction Species of {RuNO}⁶-Type Complexes. An Oxygen-Transfer Reaction Occurs in the Nitrosyl Site of cis-[Ru(NO^·)X(bpy)₂]ⁿ⁺ (X = ONO₂ for n = 1, X = CH₃CN, H₂O for n = 2) ({RuNO}⁷-Type) to Give an Identical Nitro Species
M. Mukaida, Y. Sato, H. Kato, M. Mori, D.Ooyama, H. Nagao, F. S. Howell, Bull. Chem. Soc. Jpn., 2000, 73, 85-95.