Department of Materials and Life Sciences, Faculty of Science and Technology, Sophia University
有機合成化学グループ： 鈴木(教)研究室（＆旧 増山研究室）
abstracts_2022_1
| Synthesis of O,N,O-P-multidentate ligands and their heterobimetallic complexes Noriyuki Suzuki*, Satoru Yoneyama, Keisuke Sato, Keisuke Shiba, Taichi Nakayama, Yukina Uematsu, Keigo Sakurai Journal of Organometallic Chemistry, 2022, 982, 122531. DOI: 10.1016/j.jorganchem.2022.122531 |
| Abstract: Multidentate ligands that are comprised of an O,N,O-tridentate coordinating moiety and a phosphine group were synthesized. Some heterobimetallic complexes of these ligands were prepared by a simple method, i.e., first by mixing the ligand and one metal source, then adding another metal source. The O,N,O-moiety selectively coordinated to oxophilic metals such as aluminum, titanium and niobium, while the P moiety, softer Lewis base, selectively captured late transition metals such as palladium and rhodium. Initial attempts were made on a few catalytic reactions with the heterobimetallic complexes. |
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| 有機ジルコニウム五員環アルキン、五員環アレンとCp2Zr(H)Clの反応：金属ヒドリドによる水素化反応 鈴木 教之,* 米山 智, 佐藤 敬介, 柴 圭将, 中山 太一, 植松 佑紀奈, 櫻井 啓吾 Journal of Organometallic Chemistry, 2022, 982, 122531. DOI: 10.1016/j.jorganchem.2022.122531 |
| O,N,O-三座配位構造とリン配位子をもつ多座配位子を合成した。これらの配位子を用いて異種複核錯体の合成をおこなった。溶液に、配位子、金属種1, 金属種2, の順に入れるだけでチタン、ニオブ、アルミニウムと、パラジウム、ロジウム等の複核錯体を合成することに成功した。 |