
| Synthesis of an O,N,O-C Multidentate Ligand Bearing an N-Heterocyclic Carbene Towards Heterobimetallic Complexes Noriyuki Suzuki *, Muneyasu Hara, Yuxuan Gao and Yumiko Suzuki Compounds, 2026, in press. DOI: |
| Abstract: A novel multidentate ligand with an O,N,O-tridentate ligand moiety and an N-heterocyclic carbene (NHC) was synthesized. Its palladium complex, in which the NHC part coordinates to the palladium atom, was synthesized and structurally characterized. The O,N,O-part coordinated to an early transition metal such as titanium. The Ti-Pd heterobimetallic complex was observed in solution.. |
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| N-複素環カルベンを有するO,N,O-C多座配位子の合成とヘテロ二金属錯体の形成 Noriyuki Suzuki *, Muneyasu Hara, Yuxuan Gao and Yumiko Suzuki Compounds, 2026, in press.. DOI: |
| O,N,O-三座配位子部分とN-複素環カルベン(NHC)を有する新規多座配位子を合成した。NHC部分がパラジウム原子に配位したパラジウム錯体を合成し、構造解析を行った。O,N,O部分はチタンなどの初期遷移金属に配位した。Ti-Pdヘテロ二金属錯体が溶液中で観察された。 |